我室徐海超教授在 ACIE 上发表论文：Continuous‐Flow Electrosynthesis of Benzofused S‐Heterocycles by Dehydrogenative C–S Cross‐Coupling

文章链接：https://onlinelibrary.wiley.com/doi/10.1002/anie.201901610

摘要：

Report herein is the synthesis of benzofused six‐membered S‐heterocycles through intramolecular dehydrogenative C–S coupling using a modular flow electrolysis cell. The continuous‐flow electrosynthesis not only ensures efficient product formation, but also obviates the need for transition metal catalysts, oxidizing reagent and supporting electrolyte. Reaction scale up are conveniently achieved through extended electrolysis without changing the reaction conditions and equipment.