[ACIE] 我室徐海超教授发表论文:Electrocatalytic Allylic C−H Alkylation Enabled by a Dual-Function Cobalt Catalyst

发布日期:2022年03月07日   浏览次数:

我室徐海超教授在 ACIE 上发表论文:Electrocatalytic Allylic C−H Alkylation Enabled by a Dual-Function Cobalt Catalyst

摘要:An electrocatalytic allylic C−H alkylation reaction with carbon nucleophiles is reported, which employs an easily available cobalt–salen complex as the molecular catalyst. The method is characterized by its excellent functional group tolerance, substrate compatibility with both linear and branched terminal alkenes, and scalability (up to 200 mmol scale) with a low loading of electrolyte (down to 0.05 equiv).

文章链接:https://onlinelibrary.wiley.com/doi/10.1002/anie.202115954