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[ACIE] 我室梁汉锋副教授发表论文:A Hydrazine-Nitrate Flow Battery Catalyzed by a Bimetallic RuCo Precatalyst for Wastewater Purification along with Simultaneous Generation of Ammonia and Electricity

发布日期:2023年03月20日   浏览次数:

我室梁汉锋副教授在 ACIE 上发表论文:A Hydrazine-Nitrate Flow Battery Catalyzed by a Bimetallic RuCo Precatalyst for Wastewater Purification along with Simultaneous Generation of Ammonia and Electricity

摘要:The traditional technologies for industrial and agricultural effluent treatment are often energy-intensive. Herein, we suggest an electrochemical redox strategy for spontaneous and simultaneous decontamination of wastewater and generation of both fuels and electricity at low cost. Using hydrazine and nitrate effluents as a demonstration, we propose a hydrazine-nitrate flow battery (HNFB) that can efficiently purify the wastewater and meanwhile generate both ammonia fuel and electricity with the assistance of our developed bimetallic RuCo precatalyst. Specifically, the battery delivers a peak power density of 12 mW cm-2 and continuously operates for 20 h with an ammonia yield rate of ca. 0.38 mmol h-1 cm-2 under 100 mA cm-2. The generated electricity can drive a hydrazine electrolyzer to produce hydrogen fuel. Our work provides an alternative pathway to purify wastewater and generate high value-added fuels at low cost.

文章链接:https://onlinelibrary.wiley.com/doi/10.1002/anie.202300390