我室王野教授课题组与荷兰乌特勒支大学Krijn P. de Jong教授课题组合作，在双功能催化剂上金属迁移作用机制方面取得重要进展，相关成果“Visualizing Element Migration over Bifunctional Metal-Zeolite Catalysts and its Impact on Catalysis”发表于《德国应用化学》(Angew. Chem. Int. Ed., DOI: 10.1002/anie.202107264)。采用反应耦合研究思路设计双功能催化剂可以实现CO、CO2和CH4等碳一小分子高选择性制备清洁液体燃料...

我室谢兆雄教授在 Applied Catalysis B: Environmental 上发表论文：Constructing oxide/sulfide in-plane heterojunctions with enlarged internal electric field for efficient CO2 photoreduction摘要：The internal electric field (IEF) has recently attracted intense attention in photocatalysis due to its extraordinary ability in accelerating charge separation and migration. In this work, it is found that...

我室程俊教授、廖洪钢教授、孙世刚教授在 Small methods 上发表论文：Atomic Scale Tracking of Single Layer Oxide Formation: Self-Peeling and Phase Transition in Solution摘要：Liquid phase electron microscopy (TEM) is used to track the formation of In2O3 ultrathin nanosheet in solution at atomic scale. This observation reveals that the formation of few atomic layer nanosheet goes through a complicat...

我室汪骋教授在 J. Am. Chem. Soc. 上发表论文：Neighboring Zn–Zr Sites in a Metal–Organic Framework for CO2 Hydrogenation摘要：ZrZnOx is active in catalyzing carbon dioxide (CO2) hydrogenation to methanol (MeOH) via a synergy between ZnOx and ZrOx. Here we report the construction of Zn2+–O–Zr4+ sites in a metal–organic framework (MOF) to reveal insights into the structural requirement for Me...

我室朱红平教授在 J. Am. Chem. Soc. 上发表论文：1-Aza-2,4-disilabicyclo[1.1.0]butanes with Superelongated C–N σ-Bonds摘要：Two silylene molecules oxidatively react under formal [1 + 2 + 1]-cycloaddition to the C≡N bond of nitriles to yield 1-aza-2,4-disilabicyclo[1.1.0]butanes (L)(Cl)Si[μ-η1,2-NC(p-RC6H4)]Si(Cl)(L) (L = PhC(NtBu)2, R = CF3 (2), F (3), Cl (4), Br (5)). The strongly folded bi...

​我室任斌教授在 Advanced Materials 上发表论文：Metallic Plasmonic Array Structures: Principles, Fabrications, Properties, and Applications摘要：The vast development of nanofabrication has spurred recent progress for the manipulation of light down to a region much smaller than the wavelength. Metallic plasmonic array structures are demonstrated to be the most powerful platform to realize contro...

​我室谢顺吉教授和王野教授在 Advanced Materials 上发表论文：Metal Sulfide Photocatalysts for Lignocellulose Valorization摘要：Transition metal sulfides are an extraordinarily vital class of semiconductors with a wide range of applications in the photocatalytic field. A great number of recent advances in photocatalytic transformations of lignocellulosic biomass, the largest renewable carbon reso...

我室黄小青教授在 Nano letters 上发表论文：Highly Surface-Distorted Pt Superstructures for Multifunctional Electrocatalysis摘要：Platinum (Pt) catalysts play a key role in energy conversion and storage processes, but the realization of further performance enhancement remains challenging. Herein, we report a new class of Pt superstructures (SSs) with surface distortion engineering by electrochemi...

我室陈忠教授在 J. Phys. Chem. Lett. 上发表论文：High-Resolution Reconstruction for Multidimensional Laplace NMR摘要：As a perfect complement to conventional NMR that aims for chemical structure elucidation, Laplace NMR constitutes a powerful technique to study spin relaxation and diffusion, revealing information on molecular motions and spin interactions. Different from conventional NMR adoptin...

我室Pavlo O. Dral在 Nature Reviews Chemistry 上发表论文：Molecular excited states through a machine learning lens摘要：Theoretical simulations of electronic excitations and associated processes in molecules are indispensable for fundamental research and technological innovations. However, such simulations are notoriously challenging to perform with quantum mechanical methods. Advances in machin...