我室吕鑫教授和叶龙武教授在 Chemical Science 上发表论文：Copper-catalyzed asymmetric cyclization of alkenyl diynes: method development and new mechanistic insights摘要：Metal carbenes have proven to be one of the most important and useful intermediates in organic synthesis, but catalytic asymmetric reactions involving metal carbenes are still scarce and remain a challenge. Particularly, the mech...

我室王鸣生教授在 ACS nano 上发表论文：Fast and Durable Potassium Storage Enabled by Constructing Stress-Dispersed Co3Se4 Nanocrystallites Anchored on Graphene Sheets摘要：Transition metal dichalcogenides are regarded as promising anode materials for potassium-ion batteries (PIBs) because of their high theoretical capacities. However, due to the large atomic radius of K+, the structural damage c...

我室夏海平教授和洪文晶教授在 JACS 上发表论文：Reversible Switching between Destructive and Constructive Quantum Interference Using Atomically Precise Chemical Gating of Single-Molecule Junctions摘要：Quantum interference (QI) plays an imperative role in the operation of molecular devices within the phase-coherent length, and it is vital to harness the patterns of QI, i.e., constructive and dest...

我室霍浩华教授在 Nature communications 上发表论文：Asymmetric benzylic C(sp3)−H acylation via dual nickel and photoredox catalysis摘要：Asymmetric C(sp3)−H functionalization is a persistent challenge in organic synthesis. Here, we report an asymmetric benzylic C−H acylation of alkylarenes employing carboxylic acids as acyl surrogates for the synthesis of α-aryl ketones via nickel and photor...

我室周志有教授在 Nano energy 上发表论文：Ru nanoparticles supported on partially reduced TiO2 as highly efficient catalyst for hydrogen evolution摘要：The development of low-cost yet highly efficient catalysts for hydrogen evolution reaction (HER) is crucial for large-scale clean and sustainable hydrogen production from water splitting. Tuning the interfacial structure of catalyst has emerged a...

我室杨朝勇教授在 ACIE 上发表论文：Coupling Aptamer-based Protein Tagging with Metabolic Glycan Labeling for In Situ Visualization and Biological Function Study of Exosomal Protein-Specific Glycosylation摘要：Exosomal glycoproteins play important roles in many physiological and pathological functions. However, the existing methods for studying glycosylation of exosomal proteins of interest are o...

我室王野教授课题组与荷兰乌特勒支大学Krijn P. de Jong教授课题组合作，在双功能催化剂上金属迁移作用机制方面取得重要进展，相关成果“Visualizing Element Migration over Bifunctional Metal-Zeolite Catalysts and its Impact on Catalysis”发表于《德国应用化学》(Angew. Chem. Int. Ed., DOI: 10.1002/anie.202107264)。采用反应耦合研究思路设计双功能催化剂可以实现CO、CO2和CH4等碳一小分子高选择性制备清洁液体燃料...

我室谢兆雄教授在 Applied Catalysis B: Environmental 上发表论文：Constructing oxide/sulfide in-plane heterojunctions with enlarged internal electric field for efficient CO2 photoreduction摘要：The internal electric field (IEF) has recently attracted intense attention in photocatalysis due to its extraordinary ability in accelerating charge separation and migration. In this work, it is found that...

我室程俊教授、廖洪钢教授、孙世刚教授在 Small methods 上发表论文：Atomic Scale Tracking of Single Layer Oxide Formation: Self-Peeling and Phase Transition in Solution摘要：Liquid phase electron microscopy (TEM) is used to track the formation of In2O3 ultrathin nanosheet in solution at atomic scale. This observation reveals that the formation of few atomic layer nanosheet goes through a complicat...

我室汪骋教授在 J. Am. Chem. Soc. 上发表论文：Neighboring Zn–Zr Sites in a Metal–Organic Framework for CO2 Hydrogenation摘要：ZrZnOx is active in catalyzing carbon dioxide (CO2) hydrogenation to methanol (MeOH) via a synergy between ZnOx and ZrOx. Here we report the construction of Zn2+–O–Zr4+ sites in a metal–organic framework (MOF) to reveal insights into the structural requirement for Me...