我室特聘研究员邓德会在 ACIE 上发表论文：Boosting CO2 Hydrogenation to Formate over Edge-Sulfur Vacancies of Molybdenum Disulfide摘要：Synthesis of formate from hydrogenation of carbon dioxide (CO2) is an atom-economic reaction but is confronted with challenges in developing high-performance non-precious metal catalysts for application of the process. Herein, we report a highly durable edge-rich...

我室杨扬教授和洪文晶教授在 JACS 上发表论文：Supramolecular Radical Electronics摘要：Supramolecular radical chemistry is an emerging area bridging supramolecular chemistry and radical chemistry, and the integration of radicals into the supramolecular architecture offers a new dimension for tuning their structures and functions. Although various efforts have been devoted to the fabrication of sup...

我室林海昕教授在 JACS 上发表论文：Ga-Modification Near-Surface Composition of Pt–Ga/C Catalyst Facilitates High-Efficiency Electrochemical Ethanol Oxidation through a C2 Intermediate摘要：In electrochemical ethanol oxidation reactions (EOR) catalyzed by Pt metal nanoparticles through a C2 route, the dissociation of the C–C bond in the ethanol molecule can be a limiting factor. Complete EOR pr...

我室王宇成教授和郑南峰教授在 JACS 上发表论文：Mechanism of Particle-Mediated Inhibition of Demetalation for Single-Atom Catalytic Sites in Acidic Electrochemical Environments摘要：Demetalation, caused by the electrochemical dissolution of metal atoms, poses a significant challenge to the practical application of single-atom catalytic sites (SACSs) in proton exchange membrane-based energy techno...

我室黄小青教授在 JACS 上发表论文：Highly Selective Synthesis of Monoclinic-Phased Platinum–Tellurium Nanotrepang for Direct Formic Acid Oxidation Catalysis摘要：Designing efficient formic acid oxidation reaction (FAOR) catalysts with remarkable membrane electrode assembly (MEA) performance in a direct formic acid fuel cell (DFAFC) medium is significant yet challenging. Herein, we report that t...

我室黄小青教授在 Chemical reviews 上发表论文：Strain and Surface Engineering of Multicomponent Metallic Nanomaterials with Unconventional Phases摘要：Multicomponent metallic nanomaterials with unconventional phases show great prospects in electrochemical energy storage and conversion, owing to unique crystal structures and abundant structural effects. In this review, we emphasize the progress i...

我室廖洪钢教授和田娜教授在 Nano Energy 上发表论文：In-situ constructing Bi@Bi2O2CO3 nanosheet catalyst for ampere-level CO2 electroreduction to formate摘要：Bi-based electrocatalysts are prominent candidates to achieve CO2 reduction to formate with high selectivity but suffer from unsatisfied activity, stability, and ambiguous nature of active sites. Herein, the Bi@Bi2O2CO3 nanosheet catalyst i...

我室谭元植教授在 JACS 上发表论文：Two Metastable Endohedral Metallofullerenes Sc2C2@C1(39656)-C82 and Sc2C2@C1(51383)-C84: Direct-C2-Insertion Products from Their Most Stable Precursors摘要：Endohedral metallofullerenes (EMFs) are sub-nano carbon materials with diverse applications, yet their formation mechanism, particularly for metastable isomers, remains ambiguous. The current theoretical me...

我室洪文晶教授在 Science Advances 上发表论文：Composition and sequence-controlled conductance of crystalline unimolecular monolayers摘要：Understanding how the charge travels through sequence-controlled molecules has been a formidable challenge because of simultaneous requirements in well-controlled synthesis and well-manipulated orientation. Here, we report electrically driven simultaneous syn...

我室洪文晶教授在 Nature Materials 上发表论文：Single-molecule photoelectron tunnelling spectroscopy摘要：Experimental mapping of transmission is essential for understanding and controlling charge transport through molecular devices and materials. Here we developed a single-molecule photoelectron tunnelling spectroscopy approach for mapping transmission beyond the HOMO–LUMO gap of the single di...