我室夏海平教授在 Chemical Science 上发表论文：Extension of the Simmons–Smith reaction to metal-carbynes: efficient synthesis of metallacyclopropenes with σ-aromaticity文章链接：https://pubs.rsc.org/en/content/articlelanding/2020/sc/d0sc03215h#!divAbstract摘要：The Simmons–Smith reaction offers a direct route for conversion of an alkene into a cyclopropane with a zinc carbenoid as the active ...

我室周剑章副教授和吴德印教授在 J. Am. Chem. Soc. 上发表论文：Plasmonic Hot Electron-Mediated Hydrodehalogenation Kinetics on Nanostructured Ag Electrodes文章链接：https://pubs.acs.org/doi/10.1021/jacs.0c07027摘要：An attractive field of plasmon-mediated chemical reaction (PMCR) is developing rapidly, but there is still incomplete under-standing of how to control the kinetics of such a reaction ...

我室曹泽星教授在 J. Chem. Theory Comput. 上发表论文：A Double-Well Ultra-Coarse-Grained Model to Describe Protein Conformational Transitions文章链接：https://pubs.acs.org/doi/10.1021/acs.jctc.0c00551摘要：The double-well model is usually used to describe the conformational transition between two states of protein. Since conformational changes usually occur within a relatively large timescale, c...

我室侯旭教授在 Science Advances 上发表论文：Bioinspired liquid gating membrane-based catheter with anticoagulation and positionally drug release properties文章链接：https://advances.sciencemag.org/content/6/36/eabb4700摘要：Catheters are indispensable medical devices that are extensively used in daily medical treatment. However, existing catheter materials continue to encounter many problems, s...

我室杨勇教授在 Nano Energy 上发表论文：Insights of the anionic redox in P2–Na0.67Ni0.33Mn0.67O2文章链接：https://www.sciencedirect.com/science/article/pii/S2211285520308624摘要：The search for high-energy batteries has promoted intense attention to anionic redox in layered transition metal oxides because of their ability of delivering much higher capacity than traditional cathodes. P2–Na0.67N...

我室孙世刚教授在 ACIE 上发表论文：Interfacial structure of water as a new descriptor of hydrogen evolution reaction文章链接：https://onlinelibrary.wiley.com/doi/10.1002/anie.202007567摘要：Driven by the persisting poor understanding of the sluggish kinetics of the hydrogen evolution reaction (HER) on Pt in alkaline media, a direct correlation of the interfacial water structure and activity is s...

我室曹晓宇教授在 JACS 上发表论文：Truncated Face-Rotating Polyhedra Constructed from Pentagonal Pentaphenylpyrrole through Graph Theory文章链接：https://pubs.acs.org/doi/10.1021/jacs.0c08243摘要：Discovering novel families of molecular polyhedra through graph theory has attracted increasing interest. Nevertheless, the design principles of molecular polyhedra based on graph theory remain elusive...

我室谭元植教授在 Nature Communications 上发表论文：Synthesis and assembly of extended quintulene文章链接：https://www.nature.com/articles/s41467-020-17691-7摘要：Quintulene, a non-graphitic cycloarene with fivefold symmetry, has remained synthetically elusive due to its high molecular strain originating from its curved structure. Here we report the construction of extended quintulene, which was...

近日，我室郑南峰教授、傅钢教授团队在合金催化剂的溢流加氢研究方面取得重要进展。相关成果“Facet Engineering Accelerates Spillover Hydrogenation on Highly Diluted Metal Nanocatalysts”发表于Nature Nanotechnology (DOI: 10.1038/s41565-020-0746-x).   氢溢流是催化中一个重要现象。长期以来，溢流到“惰性”载体上的氢物种是否具有催化加氢活性一直存在争议。该研究团队将单原子分散催化剂与纳米表面结构调控有机结...

近日，我室杨勇教授课题组在可充钠金属电极的固体核磁共振技术研究上取得重要进展，相关成果以“Visualizing the growth process of sodium microstructures in sodium batteries by in-situ 23Na MRI and NMR spectroscopy”为题，2020年7月27号在线发表于《自然•纳米技术》（Nature Nanotechnology DOI：10.1038/s41565-020-0749-7）。由于钠元素资源丰富且成本较低，有望应用于规模化储能电池领域，近年来安全长寿命的钠基...