我室孔祥建教授在 Small methods 上发表论文：A Giant 3d‐4f Polyoxometalate Super‐Tetrahedron with High Proton Conductivity文章链接：https://onlinelibrary.wiley.com/doi/10.1002/smtd.202000777摘要：The assembly of gigantic heterometallic metal clusters remains a great challenge for synthetic chemistry. Herein, based on the slow release strategy of lanthanide ions and in situ formation of lacunary...

我室洪文晶在 Small 上发表论文：Selective Fabrication of Single‐Molecule Junctions by Interface Engineering文章链接：https://onlinelibrary.wiley.com/doi/10.1002/smll.202004720摘要：Recent progress in addressing electrically driven single‐molecule behaviors has opened up a path toward the controllable fabrication of molecular devices. Herein, the selective fabrication of single‐molecule juncti...

我室霍浩华教授在 JACS 上发表论文：Direct Enantioselective C(sp3)–H Acylation for the Synthesis of α-Amino Ketones文章链接：https://pubs.acs.org/doi/10.1021/jacs.0c10471摘要：A direct enantioselective acylation of α-amino C(sp3)–H bonds with carboxylic acids has been achieved via the merger of transition metal and photoredox catalysis. This straightforward protocol enables cross-coupling of ...

我室汪骋教授在 ACS Central Science 上发表论文：Metal–Organic Layers for Electrocatalysis and Photocatalysis文章链接：https://pubs.acs.org/doi/10.1021/acscentsci.0c01150摘要：Metal–organic layers (MOLs) are two-dimensional analogues of metal–organic frameworks (MOFs) with a high aspect ratio and thickness down to a monolayer. Active sites on MOLs are more accessible than those on MOFs thanks ...

​我室洪文晶教授在 JACS 上发表论文：Electric Field-Induced Assembly in Single-Stacking Terphenyl Junctions文章链接：https://pubs.acs.org/doi/10.1021/jacs.0c07348摘要：Molecular assembly is crucial in functional molecular materials and devices. Among the molecular interactions that can form assemblies, stacking among π-conjugated molecular backbones plays an essential role in charge transport t...

我室杨勇教授在 Energy & Environmental Science 上发表论文：Li-rich cathodes for rechargeable Li-based batteries: reaction mechanisms and advanced characterization techniques文章链接：https://pubs.rsc.org/en/content/articlelanding/2020/ee/d0ee01694b#!divAbstract摘要：Due to their high specific capacities beyond 250 mA h g−1, lithium-rich oxides have been considered as promising cathodes for the ...

我室孙世刚教授在 JMCA 上发表论文：Insights into the Li incorporation effect in Ni/Co-free P2-type Na0.6Mn0.8Cu0.2O2 for sodium-ion batteries文章链接：https://pubs.rsc.org/en/content/articlelanding/2020/ta/d0ta08268f#!divAbstract摘要：Copper-containing composites have been widely investigated among various sodium-layered cathode materials due to the low cost and abundance of the copper element. ...

我室董全峰教授在 ACS nano 上发表论文：Turning Soluble Polysulfide Intermediates Back into Solid State by a Molecule Binder in Li–S Batteries文章链接：https://pubs.acs.org/doi/10.1021/acsnano.0c07240摘要：The shuttle effect of dissolved polysulfides produced during the operation of lithium–sulfur batteries is the most serious and fundamental problem among many challenges. We propose a strategy...

我室郑南峰教授、傅钢教授团队与北京大学江颖教授课题组密切合作在铜材料表面配位防腐技术方面取得重要进展。相关成果“Surface Coordination Layer Passivates Oxidation of Copper” 于10月14日发表在Nature, 586, 390-394。 铜是一种具有优良的导热性、导电性和延展性的重要有色金属，已被广泛应用于日常生活和工业生产中。与铝和镍等金属不同，铜表面无法形成致密、稳定的钝化层，致使铜表面会被持续氧化腐蚀。历史上，铜的...

我室程俊教授课题组在电化学界面双电层理论模拟中研究取得重要进展，相关成果以“Molecular origin of negative component of Helmholtz capacitance at electrified Pt(111)/water interface”为题发表于Science Advances (Sci. Adv. 6, eabb1219 (2020)). 双电层对于电化学界面过程的意义重大，但目前依然对其缺乏足够的微观认知。在该工作中，结合第一性原理分子动力学方法和课题组自身发展的电极电势计算方法（计算氢标准电...