我室周志有教授在 J. Am. Chem. Soc. 上发表论文：High CO-Tolerant Ru-Based Catalysts by Constructing an Oxide Blocking Layer摘要：CO poisoning of Pt-group metal catalysts is a long-standing problem, particularly for hydrogen oxidation reaction in proton exchange membrane fuel cells. Here, we report a catalyst of Ru oxide-coated Ru supported on TiO2 (Ru@RuO2/TiO2), which can tolerate 1–3% CO, enh...

我室孔祥建教授在 J. Am. Chem. Soc. 上发表论文：Magnetic 3d–4f Chiral Clusters Showing Multimetal Site Magneto-Chiral Dichroism摘要：Here, we report the molecular self-assembly of hydroxido-bridged {Ln5Ni6} ((Ln3+ = Dy3+, Y3+) metal clusters by the reaction of enantiopure chiral ligands, namely, (R/S)-(2-hydroxy-3-methoxybenzyl)-serine), with NiII and LnIII precursors. Single-crystal diffractio...

我室霍浩华教授在 J. Am. Chem. Soc. 上发表论文：Modular Access to Chiral α-(Hetero)aryl Amines via Ni/Photoredox-Catalyzed Enantioselective Cross-Coupling摘要：Chiral α-aryl N-heterocycles are commonly found in natural products, pharmaceutical agents, and chiral catalysts but remain challenging to access via asymmetric catalysis. Herein, we report a general and modular approach for the direct ...

我室孙世刚教授在 JMCA 上发表论文：Helical PdPtAu nanowires bounded with high-index facets selectively switch the pathway of ethanol electrooxidation摘要：Intensive studies have been devoted to the preparation of electrocatalysts with outstanding activity and stability for ethanol oxidation. However, the electrocatalytic efficiency is far from satisfactory for application due to the low catalyti...

我室叶龙武教授在 ACIE 上发表论文：Catalyst-Dependent Stereospecific [3,3]-Sigmatropic Rearrangement of Sulfoxide-Ynamides: Divergent Synthesis of Chiral Medium-Sized N,S-Heterocycles摘要：Medium-sized N,S-heterocycles have received tremendous interest due to their biological activities and potential medical applications. However, asymmetric synthesis of these compounds are extremely rare. Descr...

我室卓春祥教授在 Nat. Commun. 上发表论文：Stereoselective intermolecular radical cascade reactions of tryptophans or ɤ-alkenyl-α-amino acids with acrylamides via photoredox catalysis摘要：The radical cascade reaction is considered as one of the most powerful methods to build molecular complexity. However, highly stereoselective intermolecular radical cascade reactions that can produce complex...

我室侯旭教授在 Nat. Commun. 上发表论文：Host-guest liquid gating mechanism with specific recognition interface behavior for universal quantitative chemical detection摘要：Universal visual quantitative chemical detection technology has emerged as an increasingly crucial tool for convenient testing with immediate results in the fields of environmental assessment, homeland security, clinical drug ...

我室赵金保教授在 Energy Storage Materials 上发表论文：Achieving ultra-long lifespan Zn metal anodes by manipulating desolvation effect and Zn deposition orientation in a multiple cross-linked hydrogel electrolyte摘要：Aqueous zinc-ion batteries (ZIBs) have received extensive attention due to the intrinsic advantages of high safety, low cost and environmental friendliness. But detrimental side r...

我室谭元植教授和洪文晶教授在 Chemical Science 上发表论文：Charge transport through single-molecule bilayer-graphene junctions with atomic thickness摘要：The van der Waals interactions (vdW) between π-conjugated molecules offer new opportunities for fabricating heterojunction-based devices and investigating charge transport in heterojunctions with atomic thickness. In this work, we fabricate sa...

我室董全峰教授在 EEM 上发表论文：A tip-inhibitor interphase embedded with soluble polysulfides for high-voltage Li metal batteries摘要：The high-voltage battery has now become a goal in order to meet the demands for high-energy density. However, the severe side reactions between Li metal and carbonate-based electrolytes in this system result in unstable interphase, leading to non-uniform Li-ion...