我室杨晔教授在 J. Phys. Chem. Lett. 上发表论文：Ultrafast Anisotropic Evolution of Photoconductivity in Sb2Se3 Single Crystals摘要：The antimony chalcogenide crystals are composed of quasi-one-dimensional [Sb4X6]n ribbons, which lead to strong anisotropic optical and electronic properties. An attempt to exploit photoconductivity anisotropy in the device fabrication may introduce a rewarding str...

我室孙世刚教授在 Energy Environ. Sci. 上发表论文：Seizing gaseous Fe2+ to densify O2-accessible Fe–N4 sites for high-performance proton exchange membrane fuel cells摘要：Increasing the density of Fe–N4 sites in Fe–N–C materials is pivotal for enhancing the kinetics of the oxygen reduction reaction (ORR) in proton exchange membrane fuel cells (PEMFCs). Fe utilization is a vital parameter for...

我室郑南峰教授和傅钢教授在 Nature Communications 上发表论文：Atomic overlayer of permeable microporous cuprous oxide on palladium promotes hydrogenation catalysis摘要：The interfacial sites of metal-support interface have been considered to be limited to the atomic region of metal/support perimeter, despite their high importance in catalysis. By using single-crystal surface and nanocrystal as m...

我室孙世刚教授在 Chemical Engineering Journal 上发表论文：MOF-derived Single Site Catalysts with Electron-Rich Fe-N4 sites for Efficient Elimination of Trichloroacetamide DBP摘要：Herein, Fe/Co was firstly co-doped on zeolitic imidazolate framework-8 and then calcination to form electron-rich Fe-N4 single site catalysts ( eFeNSCs). The eFeNSCs are composed of FeCo nanoparticles (∼5 nm) surroun...

我室郑南峰教授在 Chem 上发表论文：Regioselective hydrogenation of alkenes over atomically dispersed Pd sites on NHC-stabilized bimetallic nanoclusters摘要：A catalyst containing atomically dispersed Pd sites on N-heterocyclic carbene (NHC)-stabilized Au nanoclusters, with the precise formula of PdAu9(NHCBn)7X2 (NHCBn is dibenzylbenzimidazolin-2-ylidene, X is Br or Cl), has been developed for th...

我室吴川六教授在 Chemical Science 上发表论文：Structure-guided design of CPPC-paired disulfide-rich peptide libraries for ligand and drug discovery摘要：Peptides constrained through multiple disulfides (or disulfide-rich peptides, DRPs) have been an emerging frontier for ligand and drug discovery. Such peptides have the potential to combine the binding capability of biologics with the stability...

我室范凤茹教授在 Chemical Science 上发表论文：In situ Raman spectroscopy reveals the structure evolution and lattice oxygen reaction pathway induced by the crystalline–amorphous heterojunction for water oxidation摘要：One of the most successful approaches for balancing the high stability and activity of water oxidation in alkaline solutions is to use amorphous and crystalline heterostructures....

我室周志有教授在 J. Am. Chem. Soc. 上发表论文：High CO-Tolerant Ru-Based Catalysts by Constructing an Oxide Blocking Layer摘要：CO poisoning of Pt-group metal catalysts is a long-standing problem, particularly for hydrogen oxidation reaction in proton exchange membrane fuel cells. Here, we report a catalyst of Ru oxide-coated Ru supported on TiO2 (Ru@RuO2/TiO2), which can tolerate 1–3% CO, enh...

我室孔祥建教授在 J. Am. Chem. Soc. 上发表论文：Magnetic 3d–4f Chiral Clusters Showing Multimetal Site Magneto-Chiral Dichroism摘要：Here, we report the molecular self-assembly of hydroxido-bridged {Ln5Ni6} ((Ln3+ = Dy3+, Y3+) metal clusters by the reaction of enantiopure chiral ligands, namely, (R/S)-(2-hydroxy-3-methoxybenzyl)-serine), with NiII and LnIII precursors. Single-crystal diffractio...

我室霍浩华教授在 J. Am. Chem. Soc. 上发表论文：Modular Access to Chiral α-(Hetero)aryl Amines via Ni/Photoredox-Catalyzed Enantioselective Cross-Coupling摘要：Chiral α-aryl N-heterocycles are commonly found in natural products, pharmaceutical agents, and chiral catalysts but remain challenging to access via asymmetric catalysis. Herein, we report a general and modular approach for the direct ...