我室孙世刚教授在 Chemical Engineering Journal 上发表论文：MOF-derived Single Site Catalysts with Electron-Rich Fe-N4 sites for Efficient Elimination of Trichloroacetamide DBP摘要：Herein, Fe/Co was firstly co-doped on zeolitic imidazolate framework-8 and then calcination to form electron-rich Fe-N4 single site catalysts ( eFeNSCs). The eFeNSCs are composed of FeCo nanoparticles (∼5 nm) surroun...

我室郑南峰教授在 Chem 上发表论文：Regioselective hydrogenation of alkenes over atomically dispersed Pd sites on NHC-stabilized bimetallic nanoclusters摘要：A catalyst containing atomically dispersed Pd sites on N-heterocyclic carbene (NHC)-stabilized Au nanoclusters, with the precise formula of PdAu9(NHCBn)7X2 (NHCBn is dibenzylbenzimidazolin-2-ylidene, X is Br or Cl), has been developed for th...

我室吴川六教授在 Chemical Science 上发表论文：Structure-guided design of CPPC-paired disulfide-rich peptide libraries for ligand and drug discovery摘要：Peptides constrained through multiple disulfides (or disulfide-rich peptides, DRPs) have been an emerging frontier for ligand and drug discovery. Such peptides have the potential to combine the binding capability of biologics with the stability...

我室范凤茹教授在 Chemical Science 上发表论文：In situ Raman spectroscopy reveals the structure evolution and lattice oxygen reaction pathway induced by the crystalline–amorphous heterojunction for water oxidation摘要：One of the most successful approaches for balancing the high stability and activity of water oxidation in alkaline solutions is to use amorphous and crystalline heterostructures....

我室周志有教授在 J. Am. Chem. Soc. 上发表论文：High CO-Tolerant Ru-Based Catalysts by Constructing an Oxide Blocking Layer摘要：CO poisoning of Pt-group metal catalysts is a long-standing problem, particularly for hydrogen oxidation reaction in proton exchange membrane fuel cells. Here, we report a catalyst of Ru oxide-coated Ru supported on TiO2 (Ru@RuO2/TiO2), which can tolerate 1–3% CO, enh...

我室孔祥建教授在 J. Am. Chem. Soc. 上发表论文：Magnetic 3d–4f Chiral Clusters Showing Multimetal Site Magneto-Chiral Dichroism摘要：Here, we report the molecular self-assembly of hydroxido-bridged {Ln5Ni6} ((Ln3+ = Dy3+, Y3+) metal clusters by the reaction of enantiopure chiral ligands, namely, (R/S)-(2-hydroxy-3-methoxybenzyl)-serine), with NiII and LnIII precursors. Single-crystal diffractio...

我室霍浩华教授在 J. Am. Chem. Soc. 上发表论文：Modular Access to Chiral α-(Hetero)aryl Amines via Ni/Photoredox-Catalyzed Enantioselective Cross-Coupling摘要：Chiral α-aryl N-heterocycles are commonly found in natural products, pharmaceutical agents, and chiral catalysts but remain challenging to access via asymmetric catalysis. Herein, we report a general and modular approach for the direct ...

我室孙世刚教授在 JMCA 上发表论文：Helical PdPtAu nanowires bounded with high-index facets selectively switch the pathway of ethanol electrooxidation摘要：Intensive studies have been devoted to the preparation of electrocatalysts with outstanding activity and stability for ethanol oxidation. However, the electrocatalytic efficiency is far from satisfactory for application due to the low catalyti...

我室叶龙武教授在 ACIE 上发表论文：Catalyst-Dependent Stereospecific [3,3]-Sigmatropic Rearrangement of Sulfoxide-Ynamides: Divergent Synthesis of Chiral Medium-Sized N,S-Heterocycles摘要：Medium-sized N,S-heterocycles have received tremendous interest due to their biological activities and potential medical applications. However, asymmetric synthesis of these compounds are extremely rare. Descr...

我室卓春祥教授在 Nat. Commun. 上发表论文：Stereoselective intermolecular radical cascade reactions of tryptophans or ɤ-alkenyl-α-amino acids with acrylamides via photoredox catalysis摘要：The radical cascade reaction is considered as one of the most powerful methods to build molecular complexity. However, highly stereoselective intermolecular radical cascade reactions that can produce complex...