我室谢顺吉教授在 ACIE 上发表论文：Photo-Driven Iron-Induced Non-Oxidative Coupling of Methane to Ethane摘要：Photo-driven CH4 conversion to multi-carbon products and H2 is attractive but challenging, and the development of efficient catalytic systems is critical. Herein, we construct a solar energy-driven iron ions redox cycle for combining CH4 conversion and H2 production. A photo-driven iron-...

我室郑南峰教授在 JACS 上发表论文：Hydrogen Bond Network Induced by Surface Ligands Shifts the Semi-hydrogenation Selectivity over Palladium Catalysts摘要：Tuning the metal–ligand interfaces of heterogeneous catalysts has emerged as an effective strategy to optimize their catalytic performance. However, improving the selectivity via organic modification remains a challenge so far. In this work,...

我室王野&谢顺吉教授团队在电催化CO还原制多碳烯烃和含氧化合物领域取得重要突破，相关成果以“Copper lattice tension boosts full-cell CO electrolysis to multi-carbon olefins and oxygenates”为题于近日发表在国际学术期刊《Chem》(DOI: 10.1016/j.chempr.2023.03.022)。精确控制C-C偶联以合成特定的C2+化合物是C1化学中极具挑战性的难题。在全电池中，将CO2直接转化为C2+往往不能兼顾高活性、选择性和高稳定性。相比之...

我室梁汉锋副教授在 Energy Environ. Sci. 上发表论文：Weakened d–p orbital hybridization in in situ reconstructed Ru/β-Co(OH)2 heterointerfaces for accelerated ammonia electrosynthesis from nitrates摘要：The electrocatalytic nitrate reduction reaction (NtrRR) has recently become an emerging technology that can convert nitrate pollutants into high-value added ammonia products in a mild manner. H...

我室王斌举教授在 J. Chem. Theory Comput. 上发表论文：O–O Bond Formation and Oxygen Release in Photosystem II Are Enhanced by Spin-Exchange and Synergetic Coordination Interactions摘要：The photosystem II (PSII)-catalyzed water oxidation is crucial for maintaining life on earth. Despite the extensive experimental and computational research that has been conducted over the past two decades, the ...

我室Pavlo O. Dral教授在 JCTC 上发表论文：Explicit Learning of Derivatives with the KREG and pKREG Models on the Example of Accurate Representation of Molecular Potential Energy Surfaces摘要：The KREG and pKREG models were proven to enable accurate learning of multidimensional single-molecule surfaces of quantum chemical properties such as ground-state potential energies, excitation energies, an...

近日，我室乔羽教授课题组围绕取代元素稳定富锂正极机制的研究取得重要进展。相关成果以“Role of Substitution Elements in Enhancing the Structural Stability of Li-Rich Layered Cathodes”为题发表在Journal of the American Chemical Society上（Doi: 10.1021/jacs.3c01999）。富锂层状氧化物阴极由于其较高的理论容量而备受关注，但是伴随着激活的O相关物种引起的电压衰减、结构畸变以及严重的电解质分解阻碍了富锂阴极...

我室黄小青教授在 Nature Communications 上发表论文：Atomic-thick metastable phase RhMo nanosheets for hydrogen oxidation catalysis摘要：Metastable phase two-dimensional catalysts provide great flexibility for modifying their chemical, physical, and electronic properties. However, the synthesis of ultrathin metastable phase two-dimensional metallic nanomaterials is highly challenging, mainly due ...

我室叶龙武教授在 ACIE 上发表论文：Construction of Axially Chiral Arylpyrroles via Atroposelective Diyne Cyclization摘要：Axially chiral biaryls widely exist in natural products and pharmaceuticals and are used as chiral ligands and catalysts in asymmetric synthesis. Compared to the well-established axially chiral 6-membered biaryl skeletons, examples of 5-membered biaryls have been quite scarce...

近日，“碳龙化学”团队报道了首例高张力且反芳香碳龙化合物-金属桥头茚。相关成果以“Isolation, Reactivity, and Tunable Properties of a Strained Antiaromatic Osmacycle”为题在线发表于《美国化学会志》（J. Am. Chem. Soc. 2023, DOI: 10.1021/jacs.3c00942）。高环张力和反芳香性是不利于环稳定存在的两种重要因素，如何实现同时包含这两种不稳定因素环系的合成对科学家们提出了更高的挑战，此外，受限于高环张力和反...