Title: Illuminating enantioselective alkyl−alkyl couplingAuthors: Weisai Zu, Xinlong Luo & Haohua Huo*Abstract: The catalytic enantioselective formation of alkyl−alkyl bonds from simple feedstock chemicals remains a formidable challenge in organic synthesis. Now, an enantioconvergent approach that couples styrenyl aziridines with unactivated olefins using a chiral nickel catalyst and visible light ...

Title: Machine Learning Reveals In-Cavity vs Surface Activity for Selective C–H Borylation by Metal-Organic Framework CatalystsAuthors: Zhaomin Su, Bingling Dai, Xue Wang, Yibin Jiang, Wenbin Lin, Cheng Wang*Abstract: Metal-organic frameworks (MOFs) provide an expansive and tunable platform for heterogeneous catalysis, yet distinguishing between catalytic reactions occurring within their pores and ...

Title: Single-atom mediated crystal facet engineering for the exceptional production of acetate in CO electrolysisAuthors: Jiacheng Liu, Yan Wen, Wei Yan, Zhongliang Huang, Xiaozhi Liu, Xuan Huang, Changhong Zhan, Yuqi Zhang, Wei-Hsiang Huang, Chih-Wen Pao, Zhiwei Hu, Dong Su, Shunji Xie, Ye Wang, Jiajia Han*, Haifeng Xiong*, Xiaoqing Huang* and Nanjun Chen*Abstract: The production of value-added liquid ...

Title: Ligand engineering of solution-processed NiOx for high-performance n–i–p perovskite photovoltaicsAuthors: Fang Cao*,Xinfeng Dai, Di Tian, Yingchen Peng, Jun Yin, Jing Li*, Ye Yang, Nanfeng Zheng* and Binghui WuAbstract: In n–i–p halide perovskite solar cells (PSCs), replacing organic p-type semiconductors with inorganic alternatives holds significant potential for enhancing long-term stability....

Title: Microdroplet Cascade Catalysis for Highly Selective Production of Propylene Glycol under Ambient ConditionsAuthors: Jianing Dong, Jiajia Xu, Zhao-Dong Meng, Zi-Ang Nan, Weixin Li, Richard N. Zare*, Zhong-Qun Tian* and Feng Ru Fan*Abstract: Conventional propylene glycol (PG) production relies on an energy-intensive two-step thermocatalytic process, contributing significantly to CO2 emissions....

Title: Electrospray Ionization Mass Spectrometry Insights into the Assembly of Lanthanide-Containing ClustersAuthors: Ming-Qiang Qi, Ming-Hao Du, Xiang-Jian Kong*, La-Sheng Long*, Lan-Sun ZhengAbstract: Atomically precise metal clusters with well-defined crystal structures have emerged as a rapidly growing field within coordination and materials chemistry. Among them, lanthanide-containing clusters ...

Title: Colocalized Raman and IR Spectroscopies via Vibrational-Encoded Fluorescence for Comprehensive Vibrational AnalysisAuthors: Zhao-Dong Meng, Tai-Rui Wu, Li-Ling Zhou, En-Ming You, Zhi-Peng Dong, Xia-Guang Zhang, Gan-Yu Chen, De-Yin Wu, Jun Yi*, Zhong-Qun TianAbstract: Vibrational spectroscopy, including Raman scattering and infrared (IR) absorption, provides essential molecular fingerprint information,...

Title: Ligand-controlled divergent asymmetric C(sp3)−H and C(sp3)−O insertion via vinyl cationsAuthors: Cui-Ting Li, Li-Gao Liu, Jia-Zheng Li, Hao-Xuan Dong, Roman A. Novikov, Ze-Shu Wang*, Xin Hong*, Bo Zhou & Long-Wu Ye*Abstract: The insertion of either C−H bond or C−O bond via bond cleavage has proven to be a very attractive strategy for the construction of C−C and C−O bonds in organic synthesis....

Title: Tunable multi-electron redox polyoxometalates for decoupled water splitting driven by sunlightAuthors: Li-Ping Cui, Shu Zhang, Yue Zhao, Xin-Yue Ge, Le Yang, Ke Li, Liu-Bin Feng, Ren-Gui Li* & Jia-Jia Chen*Abstract: It remains a great challenge to explore redox mediators with multi-electron, suitable redox potential, and stable pH buffer ability to simulate the natural solar-to-fuel process....

Title: Deciphering multi-dimensional interfacial mechanisms via organic cosolvent engineering for sustainable zinc metal batteriesAuthors: Xiaoyu Yu, Ming Chen, Junhao Wang, Shiqi Li, Haitang Zhang, Qingao Zhao, Haiyan Luo, Yaping Deng, Hanfeng Liang, Jiang Zhou, Fei Wang, Dongliang Chao, Yeguo Zou*, Guang Feng*, Yu Qiao* & Shi-Gang SunAbstract: Introducing organic cosolvent is a common and cost-effective ...