我室李剑锋教授在 ACIE 上发表论文：Unmasking the Critical Role of the Ordering Degree of Bimetallic Nanocatalysts on Oxygen Reduction Reaction by In Situ Raman Spectroscopy摘要：The critical role of the ordering degree of AuCu bimetallic catalysts were studied in situ by a shell-isolated nanoparticle-enhanced Raman spectroscopy satellite strategy and the molecular reaction mechanism is revealed...

我室徐海超教授在 ACIE 上发表论文：Electrocatalytic Allylic C−H Alkylation Enabled by a Dual-Function Cobalt Catalyst摘要：An electrocatalytic allylic C−H alkylation reaction with carbon nucleophiles is reported, which employs an easily available cobalt–salen complex as the molecular catalyst. The method is characterized by its excellent functional group tolerance, substrate compatibility wit...

我室孔祥建教授在 ACIE 上发表论文：Hierarchical Assembly of Coordination Macromolecules with Atypical Geometries: Gd44Co28 Crown and Gd95Co60 Cage摘要：The discovered giant clusters are always highly symmetric owing to the spontaneous assembly of one or two basic units. Herein we report the Gd44Co28 crown and Gd95Co60 cage, formulated as [Gd44Co28(IDA)20(OH)72 (CO3)12(OAc)28(H2O)64]⋅(ClO4)24 an...

我室侯旭教授在 ACIE 上发表论文：Carbon Dioxide Chemically Responsive Switchable Gas Valves with Protonation-Induced Liquid Gating Self-Adaptive Systems摘要：Carbon dioxide (CO2) capture and storage technologies are promising to limit CO2 emission from anthropogenic activities, to achieve carbon neutrality goals. CO2 capture requires to separate CO2 from other gases, and therefore a gas flow sys...

我室谭元植教授在 Chemical Science 上发表论文：Phenylene segments of zigzag carbon nanotubes synthesized by metal-mediated dimerization摘要：Well-studied cycloparaphenylenes (CPPs) correspond to the simplest segments of armchair CNTs, whereas the corresponding macrocyclic oligophenylene strip of zigzag CNTs is still missing. Herein, we present two series of conjugated macrocycles (CM2PP and CN2P...

我室孙世刚教授和乔羽教授在 Nano Letters 上发表论文：Nonvolatile and Nonflammable Sulfolane-Based Electrolyte Achieving Effective and Safe Operation of the Li–O2 Battery in Open O2 Environment摘要：The Li–O2 battery should operate effectively/safely in an open O2 environment for practical applications, but not trapped in sealed/closed atmosphere. However, the typical use of volatile and flamma...

我室王翔副教授在 JPCL 上发表论文：Operando Electrochemical X-ray Diffraction and Raman Spectroscopic Studies Revealing the Alkali-Metal Ion Intercalation Mechanism in Prussian Blue Analogues摘要：Prussian blue analogues are promising cathode material candidates for aqueous rechargeable metal-ion batteries. Although great efforts have been made on developing materials, there are still rare repor...

我室梁汉锋副教授在 Nano Letters 上发表论文：Electrostatic Shielding Regulation of Magnetron Sputtered Al-Based Alloy Protective Coatings Enables Highly Reversible Zinc Anodes摘要：The uncontrolled zinc dendrite growth during plating leads to quick battery failure, which hinders the widespread applications of aqueous zinc-ion batteries. The growth of Zn dendrites is often promoted by the “tip e...

我室王斌举教授在 ACS Catalysis 上发表论文：Emergence of Function from Nonheme Diiron Oxygenases: A Quantum Mechanical/Molecular Mechanical Study of Oxygen Activation and Organophosphonate Catabolism Mechanisms by PhnZ摘要：Organophosphonate (Pn) catabolism constitutes the major source of inorganic phosphate (Pi), which is essential for the synthesis of genetic and cellular components. Unlike va...

我室徐海超教授在 JACS 上发表论文：Organoelectrocatalysis Enables Direct Cyclopropanation of Methylene Compounds摘要：Cyclopropane is a prevalent structural unit in natural products and bioactive compounds. While the transition metal-catalyzed alkene cyclopropanation of functionalized compounds such as α-diazocarbonyl derivatives has been well established and provides straightforward access to ...